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The population ratio can be given by which of the following laws?

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The population ratio can be given by which of the following laws?

(a) Bohr law

(b) Beer-Lambert law

(c) Kelvin law

(d) Boltzmann law

I got this question in an interview for internship.

My query is from Electron Spin Resonance in chapter Electron Spin Resonance Spectrometers of Analytical Instrumentation

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Right answer is (d) Boltzmann law

The best I can explain: The population ratio can be given by Boltzmann law. ‘k’ is the Boltzmann constant.

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