Right option is (a) {ww^r|w=(a+b)*}
For explanation: Initially we put a special symbol ‘#’ into the empty stack. At state q1, the w is being read. In state q2, each 0 or 1 is popped when it matches the input. If any other input is given, the PDA will go to a dead state. When we reach that special symbol ‘#’, we go to the accepting state q3.