The correct answer is (a) Manganese and chloride
The best I can explain: Water splitting is catalyzed by the oxygen-evolving complex (OEC) of protein complex photosystem II (PSII), producing dioxygen gas, protons and electrons. O (2) is released into the atmosphere, sustaining all aerobic life on earth; product protons are released into the thylakoid lumen, augmenting a proton concentration gradient across the membrane; and photo-energized electrons pass to the rest of the electron-transfer pathway. The OEC contains four manganese ions, one calcium ion and (almost certainly) a chloride ion.