Correct choice is (a) =-\(\frac{1}{V}\frac{dN_A}{dt}=-\frac{dC_A}{dt}\) is valid only if A → B.
For explanation I would say: The volume of reaction mixture remains constant as the number of moles of reactant and product is the same. Hence, the number of moles per unit volume does not vary during the progress of the reaction. Hence, the number of moles per unit volume is expressed as concentration of the reactant, A.