Correct choice is (d) Protection of metals by the surficial oxide layer and Zn-carbon electrochemical reactions in the battery
To elaborate: Initially passivating metals undergoes corrosion in order to form oxide layer. These thick, dense oxide layer acts as a strong barrier and protects the inner metal against corrosion. The Zn-carbon batteries works on the principle of galvanic corrosion. It involves conversion of chemical energy into electrical energy by these electrochemical reactions.