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Heterogeneous azeotropes exist when the vapor is in equilibrium with?

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Heterogeneous azeotropes exist when the vapor is in equilibrium with?

(a) Dual liquid phase

(b) Dual Solid phase

(c) Dual Phase

(d) Triple Phase

The question was posed to me by my college director while I was bunking the class.

The question is from Azeotropic Distillation topic in portion Azeotropic and Extractive Distillation of Distillation Design

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Right answer is (c) Dual Phase

Easy explanation: Heterogeneous azeotropes exist when the vapor is in equilibrium with two liquid phases. Heterogeneous azeotropic distillation is widely used for the separation of azeotropes.

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