Correct option is (a) 48.59
To elaborate: The sine of the critical angle is the ratio of refractive index of medium 2 to that in medium 1. Thus sin θc = n2/n1. Also n = √ε, thus sin θc = √ε2/√ε1. Put ε1 = 16 and ε2 = 9, we get θc = sin^-1(3/4) = 48.59 degree.