Correct answer is (b) Air mass
To elaborate: Path length of radiation through the atmosphere to the length of path when the sun is at zenith is called Air mass.
Air mass, m = Cos (altitude angle), except for very low solar altitude angles.
m = 1; When the sun is at the zenith
m = 2; When zenith angle is 60^o
m = 3; sec (θz) for m>3.