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What is the Sulfamating agent in the following reaction: R-NH2 + R3-NSO3 ——> RNHSO3H-NR3 ?

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What is the Sulfamating agent in the following reaction: R-NH2 + R3-NSO3 ——> RNHSO3H-NR3 ?

(a) Aniline-SO3 compound

(b) Amine-SO3 compound

(c) Alkly-SO3 compound

(d) None of the mentioned

This question was posed to me during an interview.

The origin of the question is Chlorosulfonation in section Sulfonation and Sulfation of Unit Processes

1 Answer

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Correct answer is (b) Amine-SO3 compound

Best explanation: The amine-SO3 compounds also acts as a sulfamating agents: R-NH2 + R3-NSO3 ——> RNHSO3H-NR3.

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