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Isomeric compounds have no pronounced differences in ease of sulfonation.

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Isomeric compounds have no pronounced differences in ease of sulfonation.

(a) True

(b) False

I have been asked this question in final exam.

My question is from Chemical Structures topic in division Sulfonation and Sulfation of Unit Processes

1 Answer

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Right option is (b) False

To explain I would say: Isomeric compounds show pronounced differences in ease of sulfonation. The para isomer of xylene is more difficult to react than the other two; this result is in agreement with the general rule that an entering sulfonate group tends for steric reasons to avoid entering a position adjacent to other substituents, since it is fairly bulky.

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