Right option is (a) 2S/R
The best explanation: Let the pressure outside the bubble be P1, between the two layers be P2 and pressure inside the bubble be P3.
P2 – P1 = 2S/R
P3 – P2 = 2S/R ∴ P3 – P1 = 4S/R
This shows that excess pressure just inside the first layer is 2S/R while excess pressure completely inside the bubble is 4S/R.