Correct choice is (b) –2.18×10^–18 J
Explanation: The energy of an nth orbit in a hydrogen atom is given by the formula En = -RH/n^2, where is the energy of nth orbit and RH is the Rydberg constant. The energy of 1^st orbit in a hydrogen atom = -2.18 x 10^-18 J/1 = -2.18 x 10^-18 J.