Correct answer is (b) 109.5°
To explain I would say: The molecule of methane i.e. CH4 had undergone sp^3 hybridization (1 s-orbital and 3 p-orbitals combine to give 4 sp^3 orbitals). It exhibits tetrahedral geometry. In tetrahedral geometry, the angle between the bonds of corner atoms and the central atom is 109.5°.