The correct answer is (d) (P – an^2/V^2)(V – nb) = nRT
To explain I would say: (P – an^2/V^2)(V – nb) = nRT; where p is pressure, a is the magnitude of intermolecular attractive forces within a gas, n is the number of moles, v is volume, b is a van der Waal constant, R is the universal gas constant and T is temperature.