Correct choice is (a) true
To elaborate: The term alum is given to double sulphates of the type X2SO4.Y2(SO4)3.24H2O where, X represents a monovalent cation such as sodium ion, potassium ion and ammonium while why is a trivalent cation such as aluminium 3 +, chromium 3 +, ferrous 3 + and Cobalt 3 +. Lithium-ion does not form alum.