Correct option is (b) \(\frac{8}{3}\)πr^3
To explain I would say: Since particles are assumed to be spheres and volume of one sphere is \(\frac{4}{3}\)πr^3, total volume of all particles in BCC = 2 x \(\frac{4}{3}\)πr^3=\(\frac{8}{3}\)πr^3 since a BCC has 2 particles per cell.