The correct choice is (a) Aniline
The explanation is: Froth floatation is generally used for sulphide ores. It is based on the fact that sulphide ores are preferentially wetted by oils while that of the gangue is wetted by water. To a suspension of the crushed ore in water, collectors are added to enhance the non-wettability of the ore particles. Pine oil, ethyl xanthate and potassium ethyl xanthates are examples of collectors.