Right answer is (a) 60.28 minutes
The best I can explain: Given, the reaction is 75 complete so, a=75
Rate of the reaction k=0.023 min^-1
First-order integrated rate equation, k = \(\frac{2.303}{t}\)log\(\frac{100}{100-a}\)
t=\(\frac{2.303}{0.023}\)log\(\frac{100}{100-75}\) = 60.28 minutes.