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Which of the following is a vinylic halide?

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in Chemistry – Class 12 by (188k points)
Which of the following is a vinylic halide?

(a) CH2=CHCHCl2

(b) CH3CHClCH3

(c) (CH3)2C=CHCH2Cl

(d) CH3CH=CClCH2CH3

I had been asked this question during an internship interview.

My doubt stems from Haloalkanes Classification topic in division Haloalkanes and Haloarenes of Chemistry – Class 12

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Correct option is (d) CH3CH=CClCH2CH3

Easy explanation: In CH3CH=CClCH2CH3, the Cl is bonded directly to the C atom of a C-C double bond, and hence it is a vinylic halide. CH3CHClCH3 is an alkyl halide whereas CH2=CHCHCl2 and (CH3)2C=CHCH2Cl are allylic halides.

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