The correct option is (b) \(\frac {22}{7}\)
For explanation: An irrational number is expressible in the decimal form as non-terminating and non-repeating decimals.
From the given options,
π, 1.5353353335…, 2.7878878887… are non-terminating and non-repeating decimal.
Whereas, \(\frac {22}{7}\) is non-terminating but repeating decimal.