Correct answer is (a) 9.0
To explain I would say: The boiler is alkalized to pH value of 9.0 to reduce oxidization and to support the formation of a stable layer of magnetite on water side surface of the boiler protecting from oxidation. And also oxygen scavengers are used to remove residues of oxides, especially O2 & CO2 [oxygen and carbon dioxide] must be removed. Sodium hydroxide or ammonia is used for alkalization of the feed water.