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The compounds [Co(NH3)5Cl]SO4 and [Co(NH3)5(SO4)]Cl are ________ isomers.

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in Chemistry – Class 12 by (188k points)
The compounds [Co(NH3)5Cl]SO4 and [Co(NH3)5(SO4)]Cl are ________ isomers.

(a) linkage

(b) coordination

(c) ionisation

(d) solvate

The question was posed to me during a job interview.

This is a very interesting question from Isomerism in Coordination Compounds topic in section Coordination Compounds of Chemistry – Class 12

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Correct choice is (c) ionisation

Easiest explanation: The sulphate counter ion is a potential ligand and can displace the Cl atom to make the latter the counter ion.

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