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Which of the followings reagents forms an isonitrile when reacted with an alkyl halide?

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in Chemistry – Class 12 by (188k points)
Which of the followings reagents forms an isonitrile when reacted with an alkyl halide?

(a) KCN

(b) AgCN

(c) KNO2

(d) AgNO2

I have been asked this question in an interview for job.

The doubt is from Haloalkanes & Haloarenes topic in division Haloalkanes and Haloarenes of Chemistry – Class 12

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The correct option is (b) AgCN

Explanation: AgCN has a lone pair of electrons on the N atom and attacks from the N side to forms a compound of the type RNC, where R is the alkyl group.

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