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Acetic acid behaves exactly like ethanol on reaction with thionyl chloride.

(a) True

(b) False

I have been asked this question during an online interview.

The query is from Carboxylic Acids Chemical Reactions topic in portion Aldehydes, Ketones and Carboxylic Acids of Chemistry – Class 12

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The correct answer is (a) True

Explanation: Acetic acid as well as ethanol consist of an OH group and reaction with SOCl2 results in the cleavage of C-OH bond with the hydroxyl group to be replaced by Cl atom. The only difference is that acetic acid forms acetyl chloride, whereas ethanal forms ethyl chloride.

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