Right answer is (a) Cocaine
The best I can explain: Natural anesthetic is cocaine. Due to its uses in drug abuse, this is not used anymore in practices. Synthetic nitrogenous local anesthetics are procaine, benzocaine, lignocaine, cinchocaine, bucricaine. Synthetic non-nitrogenous will be benzyl alcohol and propanediol. Clove oil, phenol, chlorpromazine can also be used as a local anesthetic.